Conjugated polymers containing 2,3-dialkoxybenzene and iptycene building blocks.

نویسندگان

  • Z Zhu
  • T M Swager
چکیده

[structure: see text]. New poly(phenylene ethynylene)s (PPEs) and poly(phenylene vinylene)s (PPVs) that are highly emissive in solution and thin films were prepared utilizing palladium-catalyzed cross-coupling between new 1,4-diiodo-2,3-dialkoxybenzene- and iptycene-containing monomers. The absorption and emission spectra of the resulting polymers consistently showed a significant blue shift relative to the corresponding polymer analogues containing 2,5-dialkoxyphenylenes.

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عنوان ژورنال:
  • Organic letters

دوره 3 22  شماره 

صفحات  -

تاریخ انتشار 2001